Tetrahedron p. 14937 - 14956 (1997)
Update date:2022-09-26
Topics:
Barriault, Louis
Quellet, Stephane G.
Deslongchamps, Pierre
The synthesis and transannular Diels-Alder reaction of a chiral 14 membered trans-cis-cis (TCC) macrocyclic triene with an activated dienophile leading to an A.B.C.[6.6.6.] tricyclic compound are described. The outcome of the TADA reaction under thermal and catalyzed conditions is discussed.
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