Stereoselective synthesis of α-C-D-gluco- and D-galactopyranosyl glycosides from an isoprenoid synthon

DOI: 10.1016/S0040-4020(98)00926-0

Source and publish data:

Tetrahedron p. 14779 - 14790 (1998)

Update date:2022-08-03

Topics:

Authors:

Jegou, Anne

Pacheco, Carole

Veyrieres, Alain

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Article abstract of DOI:10.1016/S0040-4020(98)00926-0

Addition of the allylsilane Me₃SiCH₂C:CH₂CH₂CO₂Me to D-gluco and D- galactopyranosyl derivatives gives in good yields α-C-glycopyranosides which are easily converted into glycosylated β-keto esters, butenolide and dihydropyrone.

Full text of DOI:10.1016/S0040-4020(98)00926-0

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