Tetrahedron Letters p. 1193 - 1196 (1998)
Update date:2022-09-26
Topics:
Tsujishima, Hidekazu
Nakatani, Kuniko
Shimamoto, Keiko
Shigeri, Yasushi
Yumoto, Noboru
Ohfune, Yasufumi
Both (2S,1'S,2'S)- and (2S, 1'S,2'R)-isomers of 2-(2-carboxycyclobutyl)glycine (CBG-I, 1b) and (CBG-III, 2b) are synthesized in a stereoselective manner via a [2+2] photocycloaddition of α,β-unsaturated-γ-lactam 3 with ethylene in acetone. The extended type of isomer 1b showed a weak activity on group II metabotropic glutamate receptors (mGluR2) of rat brain.
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