Tetrahedron Letters p. 2455 - 2458 (1998)
Update date:2022-08-04
Topics:
Ziegler, Frederick E.
Berlin, Michael Y.
A synthesis of (+)-desmethoxymitomycin A is described. The critical step is a highly stereoselective cyclization of an aziridinyl radical to afford a tetracycle having the same relative and absolute stereochemistry as mitomycin A and C.
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