Tetrahedron Letters p. 2479 - 2482 (1998)
Update date:2022-07-29
Topics:
Giner, Jose-Luis
The biochemically important deoxysugar 1-deoxy-D-xylulose was synthesized by improved methods. D-Tartaric acid is the starting material for a synthesis which proceeds via the intermediacy of 2,3,4-tribenzyl-D- threitol. Another, highly efficient route use, the Sharpless asymmetric dihydroxylation of 5-benzyloxy-3-penten-2-one as its key step. These syntheses are especially useful-for isotopic labelling.
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