Chiral dienolate-based remote asymmetric induction: The asymmetric α- oxylation/Pd(0)-catalyzed allylic substitution sequence leading to γ-chiral α,β-unsaturated acid derivatives

DOI: 10.1016/S0040-4039(98)00770-9

Source and publish data:

Tetrahedron Letters p. 4351 - 4354 (1998)

Update date:2022-08-03

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Authors:

Sugiura, Masaharu

Yagi, Yasuhiro

Wei, Shih-Yi

Nakai, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(98)00770-9

The asymmetric α-oxylation of the dienolates derived from chiral α,β- or β,γ-unsaturated imide with dibenzyl peroxydicarbonate followed by the Pd(0) catalyzed reactions of the resulting allylic carbonate with various nucleophiles (alkylation, etherificati

Full text of DOI:10.1016/S0040-4039(98)00770-9

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