A trinuclear molybdenum cluster coordinated by o-nitrobenzoate

DOI: 10.1107/S010827019800482X

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1612 - 1615 (1998)

Update date:2022-09-26

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Authors:

Xia, Ji-Bo

Yao, Yuan-Gen

Wu, Ling

Huang, Xiao-Ying

Lu, Jia-Xi

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Article abstract of DOI:10.1107/S010827019800482X

The title compound, tris(diethyl dithiophosphato) - 1K²S,S₁ ;2K²S,S¹ ;3K²S,S¹ - μ- o- nitrobenzoato - 2KO:3KO¹-pyridine-1KN-μ₃ -thio-tri-μ-thio-1:2K²S; 1:3K²S;2:3K²S-triangulo-trimolybdenum(3 Mo-Mo), [Mo₃S₄(C₇H₄N-O₄)(C ₄H₁₀PS₂)₃(C₅H ₅N)], was synthesized in a mixed solvent of acetonitrile and ethanol by a ligand-substitution reaction in which o-nitrobenzoic acid replaces the bridging diethyl dithiophosphate (DTP) ligand. The average Mo-Mo bond distance is 2.731 (2) A. The substitution of o-nitrobenzoate for DTP shortens the Mo-Mo bond that it bridges to 2.693 (1) A.

Full text of DOI:10.1107/S010827019800482X

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