Stereoselective hydrogenation of α-sulfinyl radical generated from alkyl radical addition to α-(1-hydroxyethyl)vinyl sulfoxide

DOI: 10.1016/S0040-4039(98)01118-6

Source and publish data:

Tetrahedron Letters p. 5553 - 5556 (1998)

Update date:2022-08-05

Topics:

Authors:

Mase, Nobuyuki

Wake, Shutaro

Watanabe, Yoshihiko

Toru, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(98)01118-6

The reaction of (2S,S(s))-α-(1-hydroxyethyl)vinyl sulfoxide with alkyl radicals and tributyltin hydride gave the addition-hydrogenation products with high diastereoselectivity, whereas (2R,S(s))-α(1-hydroxyethyl)vinyl sulfoxide gave no products under simi

Full text of DOI:10.1016/S0040-4039(98)01118-6

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