Allylation reactions of acylsilanes as synthetic equivalents of aldehydes. Application of a stereocontrolled synthesis of (1S,2S,5S)-(10S)- and-(10R)-allyl myrtanol

DOI: 10.1016/S0040-4039(98)01413-0

Source and publish data:

Tetrahedron Letters p. 6737 - 6740 (1998)

Update date:2022-08-03

Topics:

Authors:

Bonini, Bianca Flavia

Comes-Franchini, Mauro

Fochi, Mariafrancesca

Mazzanti, Germana

Nanni, Cristiano

Ricci, Alfredo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)01413-0

The allylation of acylsilanes with tetraallyltin in the presence of catalytic amounts of Sc(OTf)₃ proceeded smoothly to afford the silylated homoallylic alcohols in good yields. Subsequent protiodesilylation gave the formal adducts of the corre

Full text of DOI:10.1016/S0040-4039(98)01413-0

Products guided by the article

Product name:(S)-1-((1S,2S,5S)-6,6-Dimethyl-bicyclo[3.1.1]hept-2-yl)-1-(dimethyl-phenyl-silanyl)-but-3-en-1-ol

Cas No:214277-49-3

R&D Labs maybe for 214277-49-3

Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China
Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
Anhui Sholon New Material Technology Co., Ltd.

website:http://www.sholonchem.com

Contact:+86-550-5261666

Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province

Relevant to this article

Synthesis of 4-aryl-5-nitro-1,2,3-triazoles

Doi:10.1023/B:RUJO.0000036090.61432.18
(2004)
Steric and Conformational Effects in Nicotine Chemistry

Doi:10.1021/jo00328a010
(1981)
Use of acid-labile protective groups for carbohydrate moieties in synthesis of glycopeptides related to type II collagen

Doi:10.1016/S0040-4020(98)83057-3
(1998)
An efficient and large-scale enantioselective synthesis of PNP405: A purine nucleoside phosphorylase inhibitor

Doi:10.1021/jo020256i
(2002)
Ligand-, base-, co-catalyst-free copper fluorapatite (CuFAP) as a versatile, ecofriendly, heterogeneous and reusable catalyst for an efficient homocoupling of arylboronic acid at ambient reaction conditions

Doi:10.1039/c4ra16760k
(2015)
Rediscovering an endothelin antagonist (BQ-123): A self-deconvoluting cyclic pentapeptide library

Doi:10.1021/jm9604078
(1996)

Article Doi