Allylation reactions of acylsilanes as synthetic equivalents of aldehydes. Application of a stereocontrolled synthesis of (1S,2S,5S)-(10S)- and-(10R)-allyl myrtanol

DOI: 10.1016/S0040-4039(98)01413-0

Source and publish data:

Tetrahedron Letters p. 6737 - 6740 (1998)

Update date:2022-08-03

Topics:

Authors:

Bonini, Bianca Flavia

Comes-Franchini, Mauro

Fochi, Mariafrancesca

Mazzanti, Germana

Nanni, Cristiano

Ricci, Alfredo

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Article abstract of DOI:10.1016/S0040-4039(98)01413-0

The allylation of acylsilanes with tetraallyltin in the presence of catalytic amounts of Sc(OTf)₃ proceeded smoothly to afford the silylated homoallylic alcohols in good yields. Subsequent protiodesilylation gave the formal adducts of the corre

Full text of DOI:10.1016/S0040-4039(98)01413-0

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