
Tetrahedron Letters p. 6773 - 6776 (1998)
Update date:2022-09-26
Topics:
Meijer, Michel D.
Rump, Mathias
Gossage, Robert A.
Jastrzebski, Johann H.T.B.
Van Koten, Gerard
Two new methanofullerenes have been prepared by the reaction of C60 with diazo substituted, potentially monoanionic, terdentate diamino aryl ligands, yielding a mixture of the open valence [5,6]- and closed valence [6,6]-isomers. Single isomers of the pure [6,6]-methanofullerenes were obtained by heating these mixtures in toluene solution.
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Doi:10.1007/BF00478067
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