Chemistry Letters p. 981 - 982 (1998)
Update date:2022-08-04
Topics:
Tan, Bo
Goto, Kei
Kobayashi, Junji
Okazaki, Renji
A thionitrosoarene generated by the desulfurization reaction of a stable N-thiosulfinylaniline bearing a bowl-type substituent underwent the intramolecular cyclization reaction involving the ortho-alkyl group to afford the corresponding 3,3a-dihydro-2,1-benzisothiazole. The intermediacy of the thionitrosoarene was corroborated by a trapping experiment with aniline.
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Doi:10.1039/a804954h
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(2015)