Angewandte Chemie - International Edition p. 8914 - 8918 (2009)
Update date:2022-09-26
Topics: Enantioselective Isothiourea
Joannesse, Caroline
Johnston, Craig P.
Concellon, Carmen
Simal, Carmen
Philp, Douglas
Smith, Andrew D.
Transferable skills: Enantiomerically pure isothioureas promote the 0-to C-carboxyl group transfer of oxazolyl carbonates with excellent levels of enantiocontrol (see scheme). The origin of the enantioselectivity of this process was probed mechanistically and rationalized computationally.
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