Combining Q2MM modeling and kinetic studies for refinement of the osmium-catalyzed asymmetric dihydroxylation (AD) mnemonic

DOI: 10.1016/j.jorganchem.2005.11.009

Source and publish data:

Journal of Organometallic Chemistry p. 2182 - 2198 (2006)

Update date:2022-08-03

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Authors:

Fristrup, Peter

Jensen, Gitte Holm

Andersen, Marie Louise Nygaard

Tanner, David

Norrby, Per-Ola

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Article abstract of DOI:10.1016/j.jorganchem.2005.11.009

The interactions between the substrate and the ligand in the Sharpless AD reaction have been examined in detail, using a combination of substrate competition experiments and molecular modeling of transition states. There is a good agreement between comput

Full text of DOI:10.1016/j.jorganchem.2005.11.009

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