Anomerization of methyl glycosides by acid-catalysed methanolysis: Trapping of intermediates

Article abstract of DOI:10.1080/07328309908543976

Intermediate oxocarbenium ions or other intermediates produced during acid catalyzed anomerization of some methyl glycosides were trapped by reduction with 4-methylmorpholine borane. The glycosylium ion intermediate formed on anomerization of methyl 4-O-m

Full text of DOI:10.1080/07328309908543976

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Journal of Carbohydrate Chemistry
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Anomerization of Methyl Glycosides
by Acid-Catalysed Methanolysis:
Trapping of Intermediates
Per J. Garegg , Karl-Jonas Johansson , Peter Konradsson &
Bengt Lindberg
a Department of Organic Chemistry, Arrhenius Laboratory ,
Stockholm University , S-10691 Stockholm, Sweden
b Department of Organic Chemistry, Arrhenius Laboratory ,
Stockholm University , S-10691 Stockholm, Sweden
c Department of Organic Chemistry, Arrhenius Laboratory ,
Stockholm University , S-10691 Stockholm, Sweden
d Department of Organic Chemistry, Arrhenius Laboratory ,
Stockholm University , S-10691 Stockholm, Sweden
Published online: 07 Mar 2008.
To cite this article: Per J. Garegg , Karl-Jonas Johansson , Peter Konradsson & Bengt
Lindberg (1999) Anomerization of Methyl Glycosides by Acid-Catalysed Methanolysis:
Trapping of Intermediates, Journal of Carbohydrate Chemistry, 18:1, 31-40, DOI:
10.1080/07328309908543976
To link to this article: http://dx.doi.org/10.1080/07328309908543976
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