
Tetrahedron Letters p. 247 - 250 (1993)
Update date:2022-08-03
Topics:
Spules, Tara J.
Galpin, Jason D.
Macdonald, Dwight
The charge-accelerated [3,3] sigmatropic rearrangements of 3-amino-1,5-dienes are considerably more facile than those of the corresponding 3-hydroxy-1,5-dienes, requiring reaction temperatures 85 to 140°C lower.
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