Chinese Journal of Chemistry p. 685 - 688 (2014)
Update date:2022-08-03
Topics: Column chromatography NMR spectroscopy Ligands coordination complex Oxidative Addition Reductive Elimination Substrate Scope Catalyst Loading Transmetalation Copper-Catalyzed Homogeneous Catalysis Bidentate Ligand Reaction yield C-N coupling Turnover frequency (TOF) Schlenk technique Turnover number (TON) GC-MS (Gas Chromatography-Mass Spectrometry) Chelating ligand
Su, Jinyue
Qiu, Yatao
Jiang, Sheng
Zhang, Dayong
Pyridin-2-ol-N-oxide was designed as an efficient ligand for the coupling reaction of aryl iodides, aryl bromides and aryl chlorides, respectively, with primary amines, cyclic secondary amines or N-containing heterocycles at room or moderate temperature. The catalytic system showed great functional groups tolerance and excellent selective reactivity.
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