Nucleophile-dependent stereodivergence in the Pd-catalyzed intramolecular cyclization of 2-(p-tolylsulfinyl)allylacetates

DOI: 10.1016/S0040-4039(99)00701-7

Source and publish data:

Tetrahedron Letters p. 4259 - 4262 (1999)

Update date:2022-08-03

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Authors:

Henrich, Marielouise

Delgado, Antonio

Molins, Elies

Roig, Anna

Llebaria, Amadeu

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Article abstract of DOI:10.1016/S0040-4039(99)00701-7

The palladium-catalyzed intramolecular cyclization of the sodium salts of N-Boc or N-trifluoroacetyl substituted 4-acetoxy-5-(p-tolylsulfinyl)-5-hexenylamines (1a,b) and 5-acetoxy-6-(p-tolylsulfinyl)-6-heptenylamines (2a,b) gives the corresponding 2-(1-(p

Full text of DOI:10.1016/S0040-4039(99)00701-7

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