Syntheses of novel cyclotriveratrylenophane capsules and their supramolecular complexes of fullerenes

DOI: 10.1246/cl.1999.431

Source and publish data:

Chemistry Letters p. 431 - 432 (1999)

Update date:2022-07-30

Topics:

Authors:

Matsubara, Hiroshi

Oguri, Shin-Ya

Asano, Kaori

Yamamoto, Koji

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Article abstract of DOI:10.1246/cl.1999.431

Cyclotriveratrylenophanes were synthesized and their inclusion abilities for fullerenes were examined by UV spectroscopy. From the spectra, the association constants were determined using Rose and Drago method. Cyclotriveratrylene hosts showed shape-selective properties and large association constants up to 19400±110 dm³mol^-1 for C₆₀ and 26500±260 dm³mol^-1 for C₇₀.

Full text of DOI:10.1246/cl.1999.431

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