
Bulletin of the Chemical Society of Japan p. 2285 - 2291 (1980)
Update date:2022-07-30
Topics:
Suginome, Hiroshi
Uchida, Tsutomu
Kizuka, Kazuhiko
Masamune, Tadashi
D-Nor-5α-androstan-16-one was prepared via seven steps from 16-diazo-3β-hydroxyandrost-5-en-17-one.The major products of the photolysis of its acetylhydrazone in dioxane containing oxygen were the parent ketone and 17-oxa-5α-androstan-16-one, accompanied
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