Synthesis of Vinyl Selenides or Sulfides and Ketene Selenoacetals or Thioacetals by Nickel(II) Vinylation of Sodium Benzeneselenolate or Benzenethiolate

DOI: 10.1021/jo00356a024

Source and publish data:

Journal of Organic Chemistry p. 875 - 878 (1986)

Update date:2022-08-05

Topics:

Authors:

Cristau, H. J.

Chabaud, B.

Labaudiniere, R.

Christol, H.

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Article abstract of DOI:10.1021/jo00356a024

The substitution of bromine atom on a double bond by benzeneselenolate or benzenethiolate anions is catalyzed by the bis(pyridine)nickel bromide complex.Various alkenyl selenides or sulfides and seleno- or thio acetals are prepared in good to excellent yi

Full text of DOI:10.1021/jo00356a024

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