Enantioselective syntheses of (-)-7-oxo-kolavenic acid and (-)-methyl solidagonate from (-)-verbenone

DOI: 10.1016/S0040-4039(99)01030-8

Source and publish data:

Tetrahedron Letters p. 5377 - 5378 (1999)

Update date:2022-08-02

Topics:

Authors:

Kato, Michiharu

Kosugi, Hiroshi

Ichiyanagi, Tsuyoshi

Suzuki, Takao

Kodaira, Ariko

Drechsel, Peter

Hagiwara, Hisahiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(99)01030-8

The first enantioselective synthesis of the title neo-trans-clerodanes 3 and 4b from (-)-verbenone 5 has been accomplished using the ene reaction and stereoselective conjugate addition reaction to the enone 13 as the key step.

Full text of DOI:10.1016/S0040-4039(99)01030-8

Products guided by the article

Product name:2-[(1R,2S,3R,6R)-3-hydroxy-1,2-dimethyl-6-(1-methylvinyl)cyclohexyl]ethyl acetate

Cas No:245485-69-2

R&D Labs maybe for 245485-69-2

Maithili Life Sciences

Contact:+91 9963263336

Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Wuhan Biet Co., Ltd

website:http://www.biet.com.cn/

Contact:+86-27-8369 8488

Address:No. 6, Building 21, China Merchants Fanwang, Sixin North Road, Hanyang District, Wuhan City, Hubei Province
Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China

Relevant to this article

Highly diastereoselective synthesis of (6-methylenepyrrolo[1,2-c]oxazol- 7-yl)-methylphosphonate by an application of radical reaction

Doi:10.1080/00397919908085991
(1999)
Synthesis of quinones from hydroquinone dimethyl ethers. Oxidative demethylation with cobalt(III) fluoride

Doi:10.1055/s-1999-2875
(1999)
Fused quinoline heterocycles I. First example of the 2,4-diazidoquinoline-3-carbonitrile and 1-aryl-1,5-dihydro-1,2,3,4,5,6-hexaazaacephenanthrylenes ring systems

Doi:10.1039/a901521c
(1999)
cis-Bis(phenoxyacetato-O)bis(triphenylphosphine-P)platinum(II) dichloromethane solvate

Doi:10.1107/S010827019900757X
(1999)
Synthesis of symmetrical 4,4'- and 6,6'- bis(D-glucose)-based probes as tools for the study of D-glucose transport proteins

Doi:10.1016/S0040-4039(99)01241-1
(1999)
Z-selective Horner-Wadsworth-Emmons reaction of ethyl (diarylphosphono)acetates using sodium iodide and DBU

Doi:10.1021/jo000068x
(2000)

Article Doi