Synthetic Communications p. 2540 - 2554 (2012)
Update date:2022-08-04
Topics: Imines sodium borohydride Oxime Hydrazones
Yang, Yihua
Liu, Shouxin
Li, Junzhang
Tian, Xia
Zhen, Xiaoli
Han, Jianrong
(Chemical Equation Presented) A practical method has been developed for reduction of C-N double bond in oximes, imines, and hydrazones with sodium borohydride catalyzed by Raney Ni. The reactions were carried out in basic aqueous solution, and the desired products were obtained in moderate yields after a simple procedure. This method can be applied to synthesize simpler aliphatic or aromatic amines and its analogs. Copyright Taylor & Francis Group, LLC.
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