Chemistry Letters p. 1181 - 1182 (1999)
Update date:2022-09-26
Topics:
Takahashi, Haruko
Kato, Naoko
Iwashima, Makoto
Iguchi, Kazuo
A method has been developed for determining the absolute configurations of acyclic tertiary alcohols using their 2NMA [methoxy-(2-naphthyl)acetic acid] esters. The 1H NMR spectra of (R)-and (S)-2NMA esters of model compounds were measured, and Δδ values (δR-ester - δS-ester) were calculated. The absolute configuration for tertiary hydroxy group is determined based on the sign of Δδ values like that for secondary hydroxy group.
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Doi:10.1016/S0957-4166(99)00415-2
(1999)Doi:10.1016/S0968-0896(99)00221-7
(1999)Doi:10.1055/s-2006-941472
(2006)Doi:10.1021/jo991614t
(2000)Doi:10.1080/00397910008087296
(2000)Doi:10.1039/a907759f
(2000)
