Chemistry Letters p. 1255 - 1256 (1999)
Update date:2022-08-05
Topics:
Sakai, Atsushi
Bakke, Mikio
Ohta, Hiromichi
Kosugi, Hiroshi
Sugai, Takeshi
(Rc,Ss)-1,1,1-trifluoro-3-(p-tolysulfinyl)-2-propanol (>99% e.e.), an important reagent for the asymmetric protonation of substituted enolates, was prepared (70%) from (S)-methyl p-tolyl sulfoxide. The stereoselectivity of the Yamdazyma farinosa-catalyzed
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