Selective monodesulfonylation of N,N-disulfonylarylamines with tetrabutylammonium fluoride

DOI: 10.1248/cpb.47.809

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 809 - 812 (1999)

Update date:2022-08-02

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Authors:

Yasuhara, Akito

Kameda, Mitsuyoshi

Sakamoto, Takao

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Article abstract of DOI:10.1248/cpb.47.809

The monodesulfonylation reaction of N,N-bis(methylsulfonyl)-, N,N- bis(phenylsulfonyl)-, and N,N-bis(p-tolylsulfonyl)arylamines easily proceeded using tetrabutylammonium fluoride in tetrahydrofuran under mild conditions to give the corresponding N-monosulfonylarylamines in excellent yields.

Full text of DOI:10.1248/cpb.47.809

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