Inorganic Chemistry p. 2000 - 2004 (1969)
Update date:2022-07-29
Topics:
Smith, Gary L.
Kelly, Henry C.
Salts containing bis(ligand)dihydroboron(1+) ions of the type LL′BH2+, where L and L′ are electron-donating ligands coordinated to boron through different group V or VI elements, including nitrogen, phosphorus, arsenic, and sulfur, have been prepared by displacement of halide ion from a (trialkyl donor)-haloborane adduct by the appropriate neutral ligand. Halide and hexafluorophosphate salts of the compounds have been characterized. The method is quite general for the preparation of a wide variety of boronium ions, as further illustrated by the synthesis of chelated boron(1+) ions and a dinuclear boron(2+) ion from the reaction of N,N,N′,N′-tetramethylethylenediamine with mono- and dihaloborane adducts of trimethylamine.
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Doi:10.1021/j100190a064
(1992)Doi:10.1016/S0022-328X(99)00556-2
(2000)Doi:10.1016/S0960-894X(01)00375-4
(2001)Doi:10.1007/BF00595072
()Doi:10.1021/jo01066a083
(1961)Doi:10.1039/j39700000414
(1970)