Tetrahedron p. 3009 - 3016 (1981)
Update date:2022-08-03
Topics: Alkylation Regioselectivity Yield NMR spectroscopy Ligand Chromatography Organic synthesis Reaction Mechanism Solvent Effects Stereoselectivity Catalysis Coordination Chemistry Substrate Palladium Catalysis Reaction Optimization Allylic Alcohols Metal Complexes Transition Metal Complex
Moreno-Manas, M.
Trius, A.
Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allylic system for alkyl monosubstituted allyl alcohols.The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed.
View MoreContact:0086-22-23410962
Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）
Contact:+86-533-2091422
Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.
Contact:+86-151-59920036
Address:Jinqiao Gareden, jo@fj-xinyi.com
Contact:732.938.2777
Address:5012 Industrial Road Farmingdale, NJ 07727
zhejiang huangyan wanfeng pharm chem co.ltd
Contact:+86-576- 84160728
Address:No. 5 Dazha Road, Economic,Development Zone(JiangKou), Zhejiang, China
Doi:10.1039/c29690000955
(1969)Doi:10.1021/ol005545c
(2000)Doi:10.1021/acs.joc.5b00763
(2015)Doi:10.1080/10426500008043663
(2000)Doi:10.1039/c7ob02192e
(2017)Doi:10.1016/j.bmcl.2013.09.070
(2013)
