Tetrahedron p. 3009 - 3016 (1981)
Update date:2022-08-03
Topics: Alkylation Regioselectivity Yield NMR spectroscopy Ligand Chromatography Organic synthesis Reaction Mechanism Solvent Effects Stereoselectivity Catalysis Coordination Chemistry Substrate Palladium Catalysis Reaction Optimization Allylic Alcohols Metal Complexes Transition Metal Complex
Moreno-Manas, M.
Trius, A.
Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allylic system for alkyl monosubstituted allyl alcohols.The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed.
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