Behavior of 2-substituted and 2,6-disubstituted benzoyloxyl radicals. Electronic and steric effects of the substituents

DOI: 10.1016/S0040-4039(00)73422-8

Source and publish data:

Tetrahedron Letters p. 6321 - 6324 (1994)

Update date:2022-08-04

Topics:

Authors:

Wang Wang

Wang, Jun

Tsuchiya

Tsuchiya, Masahiro

Sakuragi

Sakuragi, Hirochika

Tokumaru

Tokumaru, Katsumi

Itoh Itoh

Itoh, Hiroki

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Article abstract of DOI:10.1016/S0040-4039(00)73422-8

In contrast to 2-methylbenzoyloxyl radicals, 2,6-dimethylbenzoyloxyl and 2,4,6-trimethyl-benzoyloxyl radicals decarboxylate efficiently rather than transfer a hydrogen atom, as observed by transient absorption spectroscopy and product distribution.

Full text of DOI:10.1016/S0040-4039(00)73422-8

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