A Novel o-Iminophenyl Anion Route to Heterocycles and Ortho-Substituted Anilines

DOI: 10.1021/jo00128a040

Source and publish data:

Journal of Organic Chemistry p. 7625 - 7630 (1995)

Update date:2022-08-04

Topics:

Authors:

Katritzky, Alan R.

Zhang, Guifen

Jiang, Jinlong

Steel, Peter J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00128a040

Ring opening of lithio derivatives of N-(α-alkoxyalkyl)benzotriazoles 9 and 22 and subsequent extrusion of nitrogen at -78 deg C gave novel o-iminophenyl anions which enable synthetically useful preparations of ortho-substituted anilines (19 and 25) and of benzoheterocycles (14, 20, 21, 24, and 26).

Full text of DOI:10.1021/jo00128a040

Products guided by the article

Product name:2-Phenyl-4-p-tolyl-4H-3,1-benzoxazine

Cas No:28586-64-3

R&D Labs maybe for 28586-64-3

Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China
NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai

Relevant to this article

A general acid-catalyzed anion breakdown associated with an E1cB reaction in the hydrolysis of aryl N-(substituted phenylsulfonyl)carbamates

Doi:10.1021/ja00105a020
(1994)
Facile synthesis of L-3,4-didehydrovaline constituting an antibiotic, phomopsin A

Doi:10.1055/s-2000-6382
(2000)
Synthesis of β-alkyl cyclopentanones in high enantiomeric excess via copper-catalyzed asymmetric conjugate reduction [17]

Doi:10.1021/ja0009525
(2000)
Carbon-carbon bond formation in the reductive coupling of trifluoroacetonitrile and pentafluorobenzonitrile - Synthetic routes to new perfluoroalkyl- and perfluoroaryl-substituted α-diimines: Versatile synthons for heterocycle synthesis

Doi:10.1016/j.ica.2004.09.002
(2004)
Doi:10.1002/zaac.19754140308
(1975)
Doi:10.1016/S0022-328X(00)84488-5
(1970)

Article Doi