A Novel o-Iminophenyl Anion Route to Heterocycles and Ortho-Substituted Anilines

DOI: 10.1021/jo00128a040

Source and publish data:

Journal of Organic Chemistry p. 7625 - 7630 (1995)

Update date:2022-08-04

Topics:

Authors:

Katritzky, Alan R.

Zhang, Guifen

Jiang, Jinlong

Steel, Peter J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00128a040

Ring opening of lithio derivatives of N-(α-alkoxyalkyl)benzotriazoles 9 and 22 and subsequent extrusion of nitrogen at -78 deg C gave novel o-iminophenyl anions which enable synthetically useful preparations of ortho-substituted anilines (19 and 25) and of benzoheterocycles (14, 20, 21, 24, and 26).

Full text of DOI:10.1021/jo00128a040

Products guided by the article

Product name:2-Phenyl-4-p-tolyl-4H-3,1-benzoxazine

Cas No:28586-64-3

R&D Labs maybe for 28586-64-3

Shenyang NovPharm Technology Co., Ltd.

Contact:.+86-24-24165786

Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
chengdu firsterchem Pharmaceutical Co., Ltd.

Contact:028-66825849

Address:chengdu
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China
Wuhan Yitongtai Science and Technology Co.,Ltd.

Contact:+86-27-88933550

Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China

Relevant to this article

A general acid-catalyzed anion breakdown associated with an E1cB reaction in the hydrolysis of aryl N-(substituted phenylsulfonyl)carbamates

Doi:10.1021/ja00105a020
(1994)
Facile synthesis of L-3,4-didehydrovaline constituting an antibiotic, phomopsin A

Doi:10.1055/s-2000-6382
(2000)
Synthesis of β-alkyl cyclopentanones in high enantiomeric excess via copper-catalyzed asymmetric conjugate reduction [17]

Doi:10.1021/ja0009525
(2000)
Carbon-carbon bond formation in the reductive coupling of trifluoroacetonitrile and pentafluorobenzonitrile - Synthetic routes to new perfluoroalkyl- and perfluoroaryl-substituted α-diimines: Versatile synthons for heterocycle synthesis

Doi:10.1016/j.ica.2004.09.002
(2004)
Doi:10.1002/zaac.19754140308
(1975)
Doi:10.1016/S0022-328X(00)84488-5
(1970)

Article Doi