Tetrahedron Letters p. 35 - 38 (1991)
Update date:2022-08-03
Topics:
Raban, Morton
Quin, John
Belguise, Alain
A cyclohexane pro-ionophore is held in one chair form (non-ionophoric) by a large, tertiary, ketal moiety.Upon hydrolysis the acetyl group is small enough to be axial and the cyclohexane ring can flip to an ionophoric conformation.
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