Journal of Organic Chemistry p. 6372 - 6376 (1993)
Update date:2022-07-31
Topics:
Reed, Gregg A.
Dimmel, Donald R.
Malcolm, Earl W.
The reaction of a benzyl aryl ether (3) with selected ions was studied to determine relative nucleophilicities at 195 deg C in water.Nucleophilic displacement by the ions ocurred at the benzyl carbon to liberate a phenolic group.The primary products of the displacement were independently synthesized and reacted in alkali to determine their stability.Hydrosulfide ion was 20 times more reactive than hydroxide ion with this substrate, while anthrahydroquinone ion was 17 times more reactive.
View MoreSuZhou Ascepion Pharmaceuticals, Inc.(expird)
Contact:0512-86881668
Address:Building C,68Xingqing Road,Suzhou,China.
ShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Cangzhou Senary Chemical Science-tech Co., Ltd
Contact:+86-317-3563899, 3563699
Address:168 Jinde Road, Cangzhou, Hebei, China
Contact:0086-22-2822 1962 / 2822 1963
Address:B-808, No. 1, North-South Street, Hexi District,
Zhejiang Chemicals Import & Export Corporation
Contact:86-571-87043088
Address:No.37,Qingchun Road,Hangzhou,China
Doi:10.1007/BF01152074
(1970)Doi:10.1007/s12039-010-0028-5
(2010)Doi:10.1016/j.tet.2020.131255
(2020)Doi:10.1016/S0040-4039(00)70814-8
(1968)Doi:10.1016/S0040-4039(01)88533-6
(1969)Doi:10.1021/ja00545a061
(1980)
