Journal of Organic Chemistry p. 6372 - 6376 (1993)
Update date:2022-07-31
Topics:
Reed, Gregg A.
Dimmel, Donald R.
Malcolm, Earl W.
The reaction of a benzyl aryl ether (3) with selected ions was studied to determine relative nucleophilicities at 195 deg C in water.Nucleophilic displacement by the ions ocurred at the benzyl carbon to liberate a phenolic group.The primary products of the displacement were independently synthesized and reacted in alkali to determine their stability.Hydrosulfide ion was 20 times more reactive than hydroxide ion with this substrate, while anthrahydroquinone ion was 17 times more reactive.
View MoreContact:+86-15995924277
Address:WuZhongOu suzhou new south road 89
Rugao Jinling Chemical Co., Ltd.(expird)
Contact:0086-513-68005586
Address:Lianluo new village huangshi town Rugao city Jiangsu Province.
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD
website:http://www.jinjingroup.com
Contact:86-574-13989382828
Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Contact:+86-0311-84455288-844
Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Shanghai ZaiQi Bio-Tech Co., Ltd.,
Contact:+86-21-5482 4098
Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Doi:10.1007/BF01152074
(1970)Doi:10.1007/s12039-010-0028-5
(2010)Doi:10.1016/j.tet.2020.131255
(2020)Doi:10.1016/S0040-4039(00)70814-8
(1968)Doi:10.1016/S0040-4039(01)88533-6
(1969)Doi:10.1021/ja00545a061
(1980)
