Journal of Organic Chemistry p. 6372 - 6376 (1993)
Update date:2022-07-31
Topics:
Reed, Gregg A.
Dimmel, Donald R.
Malcolm, Earl W.
The reaction of a benzyl aryl ether (3) with selected ions was studied to determine relative nucleophilicities at 195 deg C in water.Nucleophilic displacement by the ions ocurred at the benzyl carbon to liberate a phenolic group.The primary products of the displacement were independently synthesized and reacted in alkali to determine their stability.Hydrosulfide ion was 20 times more reactive than hydroxide ion with this substrate, while anthrahydroquinone ion was 17 times more reactive.
View MoreContact:(86) 731 88718666
Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
Daicel Chiral Technologies (China)CO.,LTD
Contact:021-5046-0086*8
Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Zhenjiang Haitong Chemical Industry Co., Ltd.
Contact:+86 (511) 8448-0369
Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Taizhou KEDE Chemical.Co.,Ltd.
Contact:86-576-84613060
Address:Jiangkou Chemical Zoon
SuZhou Hua-Emy Chemical Import and Export Co., LTD.
Contact:+86-512-88804994; +86-512-88804550;
Address:710, Building B, International Trade Center, 12 Huanghelu, Changshu, Jiangsu,China
Doi:10.1007/BF01152074
(1970)Doi:10.1007/s12039-010-0028-5
(2010)Doi:10.1016/j.tet.2020.131255
(2020)Doi:10.1016/S0040-4039(00)70814-8
(1968)Doi:10.1016/S0040-4039(01)88533-6
(1969)Doi:10.1021/ja00545a061
(1980)