Journal of the American Chemical Society p. 773 - 775 (2002)
Update date:2022-08-04
Topics:
Layton, Mark E.
Morales, Carl A.
Shair, Matthew D.
An enantioseletive, biomimetic synthesis of (-)-longithorone A has been achieved using an intermolecular/transannular Diels-Alder sequence which provides some support for the proposed biosynthesis. The cycloaddition precursors were two [12]-paracyclophanes that were constructed with atropisomer control during ene-yne metathesis macrocyclizations. Copyright
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