Journal of the American Chemical Society p. 19844 - 19849 (2020)
Update date:2022-08-03
Topics: Enantioselective Organic synthesis Unactivated Alkenes Ni-Catalyzed
Li, Yue
Luan, Yu-Xin
Qi, Shao-Long
Wang, Rong-Hua
Ye, Mengchun
Zhang, Feng-Ping
A carbamoyl fluoride-enabled enantioselective Ni-catalyzed carbocarbamoylation of unactivated alkenes was developed, providing a broad range of chiral γ-lactams bearing an all-carbon quaternary center in 45-96% yield and 38-97% ee.
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