Russian Chemical Bulletin p. 1753 - 1756 (2000)
Update date:2022-09-26
Topics:
Bredikhina, Z. A.
Pashagin, A. V.
Bredikhin, A. A.
The reactions of 4-chloromethyl-1,3,2-dioxathiolane 2-oxides with PhONa in EtOH are accompanied by ring opening under the action of the ethoxide ion rather than leading to a rearrangement of the starting molecule as has been assumed previously. Under conditions precluding competition with other nucleophiles, the phenoxide anion smoothly replaces the chlorine atom in chloromethyl-substituted cyclic sulfites.
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