1-diphenylphosphonio-1-methoxymethyllithium, a useful reagent for the synthesis of aldehydes from hindered ketones

DOI: 10.1016/0040-4039(80)80227-9

Source and publish data:

Tetrahedron Letters p. 3535 - 3538 (1980)

Update date:2022-07-30

Topics:

Authors:

Corey Corey

Tius, Marcus A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(80)80227-9

A new reagent, 1-diphenylphosphonio-1-methoxymethyllithium, has been found to be highly effective for the transformation R₂CO → R₂CHCHO with sterically hindered, enolizable ketones.

Full text of DOI:10.1016/0040-4039(80)80227-9

Products guided by the article

Product name:1-Isopropyl-2-[1-methoxy-meth-(E)-ylidene]-4-methyl-cyclohexane

Cas No:343791-47-9

R&D Labs maybe for 343791-47-9

Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Shanghai better-in Medical Technology Co.,LTD.

Contact:+86-21-38921049

Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Xi'an Herbland Tech Inc.

Contact:+86-29-88710656

Address:South Tai bai Road, High Tech Development Zone, Xi'an China

Relevant to this article

New chiral phosphine-amide ligands in palladium-catalysed asymmetric allylic alkylations

Doi:10.1016/S0957-4166(01)00037-4
(2001)
Copper-catalyzed radical methylation/C-H amination/oxidation cascade for the synthesis of quinazolinones

Doi:10.1021/acs.joc.5b00191
(2015)
Synthesis and characterization of transition metal complexes with benzimidazolyl-2-hydrazones of o-anisaldehyde and furfural

Doi:10.5012/jkcs.2011.55.6.926
(2011)
Electron Affinities from Electron-Transfer Equilibria : A(-) + B = A + B(-)

Doi:10.1021/ja00302a005
(1985)
Further studies on palladium-catalyzed bismetallative cyclization of enynes in the presence of Bu₃SnSiMe₃

Doi:10.1016/S0022-328X(03)00601-6
(2003)
A joint experimental and theoretical investigation on the oxidative coupling of resveratrol induced by copper and iron ions

Doi:10.1016/j.ijms.2012.05.010
(2012)

Article Doi