1-diphenylphosphonio-1-methoxymethyllithium, a useful reagent for the synthesis of aldehydes from hindered ketones

DOI: 10.1016/0040-4039(80)80227-9

Source and publish data:

Tetrahedron Letters p. 3535 - 3538 (1980)

Update date:2022-07-30

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Authors:

Corey Corey

Tius, Marcus A.

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Article abstract of DOI:10.1016/0040-4039(80)80227-9

A new reagent, 1-diphenylphosphonio-1-methoxymethyllithium, has been found to be highly effective for the transformation R₂CO → R₂CHCHO with sterically hindered, enolizable ketones.

Full text of DOI:10.1016/0040-4039(80)80227-9

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