Journal of Organometallic Chemistry p. 407 - 420 (1997)
Update date:2022-08-02
Topics:
Antelmann, Bjoern
Winterhalter, Ute
Huttner, Gottfried
Janssen, Bernd Christian
Vogelgesang, Joachim
Different routes to tripod ligands CH3C(CH2C5H5)(CH2PR′2)(CH2PR″2), 5, containing a cyclopentadienyl unit and two additional donor groups are described. The syntheses involve CH2OCH2C (CH3)CH2C5H5), 2, or CH3C(CH2Cl)(CH2Br)(CH2C5H5), 12, respectively as intermediates. The compounds 2 and 12 respectively are obtained from CH2OCH2C(CH3)(CH2OSO2CH3), 1, or CH3C(CH2Cl)(CH2Br)(CH2OSO2CF3), 11, by reaction with CpMgCl. The capability of the ligand 5 to coordinate to a transition metal via all its three donor groups is documented by the analytical, spectroscopical and X-ray structural characterisation of CH3C(CH2-η5-C5H4)(CH2PPh2)2Mn(CO), 13.
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)
Contact:86 512 57910558
Address:qianjin M road
NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD
Contact:86-0951-7815345
Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
A.M FOOD CHEMICAL CO., LIMITED
Contact:86-531-87100375
Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.
Contact:+86-21-61353236
Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Ji'nan Orgachem Pharmaceutical Co.,Ltd
Contact:+86-531-82687810
Address:Jinan
Doi:10.1039/b009567m
(2001)Doi:10.1002/chem.201702278
(2017)Doi:10.1021/bi00879a008
(1965)Doi:10.1016/j.ica.2004.09.039
(2005)Doi:10.1021/jo010001p
(2001)Doi:10.1002/anie.201306094
(2013)
