PHOTOREACTIONS OF QUININE IN AQUEOUS CITRIC ACID SOLUTION. PART 2. SOME END-PRODUCTS

DOI: 10.1016/S0040-4020(01)81448-4

Source and publish data:

Tetrahedron p. 5905 - 5910 (1988)

Update date:2022-07-30

Topics:

Authors:

Laurie, W. A.

McHale, D.

Saag, K.

Sheridan, J. B.

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Article abstract of DOI:10.1016/S0040-4020(01)81448-4

A novel spiro-compound derived from 2',4'-bis-(1,3-dicarboxy-2-hydroxyprop-2-yl)-1',4'-dihydroquinine has been identified as a major end-product of the irradiation of quinine in aqueous citric acid solution. 7'-(1,3-Dicarboxy-2-hydroxyprop-2-yl)deoxyquinine and products arising from the cleavage of quinine at C-9 were also detected in the reaction mixture.

Full text of DOI:10.1016/S0040-4020(01)81448-4

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