Helvetica Chimica Acta p. 1989 - 1995 (2001)
Update date:2022-08-05
Topics:
Blitzke, Torsten
Baranovsky, Alexander
Schneider, Bernd
(4-Carboxybutyl)carbamates 5 and 6, as well as 10, derived from 10-O-deacetylbaccatin III (1) and paclitaxel (2), respectively, were synthesized by reaction of unprotected 1 and 2′-O-(methoxyacetyl)paclitaxel (8), respectively, with trimethylsilyl 5-isocyanatopentanoate in good yields. The carbamoyl-taxoids were conjugated to bovine-serum albumin and analyzed by MALDI-TOF mass spectrometry.
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