Journal of Physical Chemistry p. 1056 - 1059 (1990)
Update date:2022-08-02
Topics:
Falvey, Daniel E.
Khambatta, Binaifer S.
Schuster, Gary B.
The neophyl-like rearrangment of alkoxy radicals was examinde by means of picosecond time scale absorption spectroscopy.The triphenylmethoxy radical (Ph3CO.) rearranges to form the α-phenoxydiphenylmethyl radical (Ph2COPh.) with a rate constant greater than 5 x 1010 s-.The rearrangment of 1,1-diphenylethoxy radical (PhCH3CO.) was also examined.In acetonitrile solution, an intermediate is formed in less than 17 ps and then decays with a lifetime of 312 ns.It is proposed that this intermediate is a brigded spiro<2.6>octadiene-type radical.
View MorePure Chemistry Scientific Inc.
Contact:+1-857-366-7588
Address:14905 SW freeway street #232, Sugarland, TX 77478, USA
Hubei Lingsheng Pharmaceuticals Co., Ltd.
Contact:+86-0710-3538058
Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Wuxi Innopal International Trade CO.,LTD
Contact:+86-510-80711901-8003
Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
website:http://www.angchenchem.com
Contact:+86-510-88302099 82327577
Address:Rm. 404/405, Floor 4th, No. 983 FengXiang Road, Wuxi, China
Contact:18710867521(wechat)
Address:Rm10516,Galaxy Tech Building #2,No.25 Tangyan Rd,Hi-Tech Zone,Xi'an, China
Doi:10.1039/jr9650002651
(1965)Doi:10.1248/yakushi1947.92.9_1117
(1972)Doi:10.1016/j.saa.2011.06.010
(2011)Doi:10.1021/jacs.1c02117
(2021)Doi:10.1016/j.bmc.2020.115877
(2021)Doi:10.14233/ajchem.2017.20626
(2017)
