Tetrahedron p. 2269 - 2272 (1981)
Update date:2022-07-30
Topics:
Meyer, G.
Viout, P.
The oximation of p-nitrophenylacetate by benzaldoximates in aqueous solution is catalyzed by CTAB micelles.The catalysis is more effective when the base strength of the oximate decreases; the reactivity of benzaldoximates is not dependent on their basicity.Our data may be interpreted in terms of orbital-controlled reactions, with interactions between both the n and ? occupied orbitals of the oximates and the LUMO of the acetate.
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