A New Route to 1,3-Dienes using 3-Methylene-2,3-dihydrothiophene S,S-Dioxide as an Allyl Sulphone and Michael Acceptor: Synthesis of (+/-)-Ipsenol

DOI: 10.1039/c39890000295

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 295 - 297 (1989)

Update date:2022-08-04

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Authors:

Nomoto, Takashi

Takayama, Hiroaki

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Article abstract of DOI:10.1039/c39890000295

Substituted 2,5-dihidrothiophene S,S-dioxides, which are stable precursors of the corresponding buta-1,3-dienes, were prepared via reactions of 3-methylene-2,3-dihydrothiophene S,S-dioxide with electrophiles and nucleophiles; this method was appiled to the synthesis of (+/-)-ipsenol.

Full text of DOI:10.1039/c39890000295

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