Bulletin of the Chemical Society of Japan p. 1988 - 1990 (1991)
Update date:2022-08-03
Topics:
Mizuno, Masafumi
Funahashi, Shigenobu
Nakasuka, Noriyuki
Tanaka, Motoharu
Activation paramaters for solvent exchange of the title complex in N,N-dimethylformamide (DMF) have been determined as follows: k(25 deg C) = (3.4 +/- 0.2) x 107 s-1, ΔH(excit.) = 18 +/- 3 kJ mol-1, ΔS(excit.) = -40 +/- 10 J K-1 mol-1, and ΔV(excit.) = 10 +/- 2 cm3 mol-1.The positive value of ΔV(excit.) indicates that the DMF exchange proceeds via a dissociative interchange mechanism.
Shenyang Xinyihan Chemical Technology Co., Ltd.
Contact:+86-18525026267
Address:362, aigongbeijei street 23 , tiexi district,Shenyang, Liaoning, China
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.
Contact:86-022-66880623
Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)
Contact:+86 021 50106671
Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park
Contact:86-310-8067016
Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Zibo Kunran Enterprises Co. LTD
website:http://www.kunranchem.com
Contact:0086 533 5200669
Address:No. 96 Jinjing Avenue, Zibo, Shandong, China
Doi:10.1021/ja00099a015
(1994)Doi:10.1016/S0008-6215(01)00255-5
(2001)Doi:10.1021/jm0155188
(2001)Doi:10.1021/ja0122849
(2002)Doi:10.1021/ja00815a041
(1974)Doi:10.1021/ja0318380
(2004)
