Journal of Organic Chemistry p. 786 - 790 (1988)
Update date:2022-08-05
Topics:
Newkome, George R.
Joo, Young J.
Evans, David W.
Pappalardo, Sebastiano
Fronczek, Frank R.
A series of bis(2-heteroaryl)acetonitriles were synthesized, characterized, and transformed into the corresponding bis(2-heteroaryl)methanes, which can be readily oxidized with SeO2 in glacial acetic acid to the respective ketones.These disubstituted acetonitriles are ideal precursors to heterocalixarenes.The configuration in the solid state of meso-cyano compound 16 was ascertained by an X-ray crystal structure.
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