The selectivities and the mechanism on highly efficient epoxidation of olefins with 2,6-disubstituted pyridine N-oxides catalyzed by ruthenium porphyrin

DOI: 10.1016/S0040-4039(00)92231-7

Source and publish data:

Tetrahedron Letters p. 2521 - 2524 (1992)

Update date:2022-08-05

Topics:

Authors:

Ohtake Ohtake

Higuchi Higuchi

Hirobe Hirobe

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Article abstract of DOI:10.1016/S0040-4039(00)92231-7

Several remarkable selectivities in competitive epoxidations using a ruthenium porphyrin/2,6-disubstituted pyridine N-oxide system were observed. The proposal that the active intermediate of this system differed from the trans-dioxo complex of ruthenium porphyrin was indicatesd.

Full text of DOI:10.1016/S0040-4039(00)92231-7

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