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A synthesis of 7alpha-hydroxyandrost-4-ene-3,17-dione.

DOI: 10.1016/S0039-128X(76)90096-9

Source and publish data:

Steroids p. 603 - 608,605, 607 (1976)

Update date:2022-09-26

Topics:

Authors:

HossainHossain

KirkKirk

MitraMitra

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Article abstract of DOI:10.1016/S0039-128X(76)90096-9

The first convenient chemical synthesis of 7alpha-hydroxyandrost-4-ene-3,17-dione is reported. Androsta-4,6-diene3, 17-dione was converted into its 6alpha, 7alpha-epoxy-derivative; reduction of the epoxide with aluminum amalgam gave 7alpha-hydroxyandrost-4-ene-3,17-dione. This reducing agent is more efficient than chromous acetate for the purpose.

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Full text of DOI:10.1016/S0039-128X(76)90096-9

Products guided by the article

Product name:(8R,9S,10R,13S)-10,13-dimethyl-9,10,11,12,13,14,15,16-octahydro-1H-cyclopenta[a]phenanthrene-3,17(2H,8H)-dione

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