Acylation of alcohols with acetic anhydride catalyzed by TaCl5: Some implications in kinetic resolution

DOI: 10.1016/S0040-4039(98)00465-1

Source and publish data:

Tetrahedron Letters p. 3263 - 3266 (1998)

Update date:2022-08-05

Topics:

Authors:

Chandrasekhar

Ramachander

Takhi, Mohamed

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Article abstract of DOI:10.1016/S0040-4039(98)00465-1

TaCl₅ and TaCl₅-Silica gel have been effectively used as Lewis acid catalysts for acetylation of alcohols. Also TaCl₅-Chiral ligands have been used for kinetic resolution of 2°alcohols albeit in low ees.

Full text of DOI:10.1016/S0040-4039(98)00465-1

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