Acylation of alcohols with acetic anhydride catalyzed by TaCl5: Some implications in kinetic resolution

DOI: 10.1016/S0040-4039(98)00465-1

Source and publish data:

Tetrahedron Letters p. 3263 - 3266 (1998)

Update date:2022-08-05

Topics:

Authors:

Chandrasekhar

Ramachander

Takhi, Mohamed

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00465-1

TaCl₅ and TaCl₅-Silica gel have been effectively used as Lewis acid catalysts for acetylation of alcohols. Also TaCl₅-Chiral ligands have been used for kinetic resolution of 2°alcohols albeit in low ees.

Full text of DOI:10.1016/S0040-4039(98)00465-1

Products guided by the article

Product name:2-isopropyl-5-methylcyclohexyl acetate

Cas No:42241-42-9

R&D Labs maybe for 42241-42-9

NingBO Hong Xiang Biochem.Co.Ltd

website:http://www.hxbiochem.com

Contact:0574-66003444

Address:Ning Bo Bei Lun
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
Xiamen Kaijia Imp & Exp Co., Ltd.

Contact:86-592-5101177

Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
Jinan Baozhao Pharmaceutical Co., Ltd

Contact:0086-531-86397156 82371858 82371868

Address:Huaneng Road, Jinan, Shandong ,China

Relevant to this article

Doi:10.1246/bcsj.46.2156
(1973)
Synthesis of Allylic Alcohols via Palladium-Catalyzed Cross-Coupling of Vinylic Epoxides and Aryl or Vinylic Halides and Triflates

Doi:10.1021/jo00056a003
(1993)
Direct access to α-sulfenylated amides/esters: Via sequential oxidative sulfenylation and C-C bond cleavage of 3-oxobutyric amides/esters

Doi:10.1039/c7cc09026a
(2018)
A new class of star-shaped discotic liquid crystal containing a 2, 4, 6-triphenyl-1, 3, 5-triazine unit as a core

Doi:10.1246/bcsj.75.615
(2002)
Doi:10.1021/ja00949a015
(1965)
Oxyaniliniums as acetylcholinesterase inhibitors for the reversal of neuromuscular block

Doi:10.1016/S0960-894X(01)00703-X
(2002)

Article Doi