Chemistry Letters p. 145 - 148 (1985)
Update date:2022-08-04
Topics:
Nomoto, Shinya
Harada, Kaoru
When a hydrogen-oxygen flame was kept in contact with an aqueous formic acid solution of unsaturated amines, carboxylation onto a double bond took place.This reaction revealed to be initiated by addition of a hydrogen atom to the double bond followed by coupling of the resulted substrate radical with a carboxyl radical.
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