Rearrangement of Carboxylates derived from N-Acetyl-N-nitroso-&α-amino-acids

DOI: 10.1039/c39810000297

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 297 - 299 (1981)

Update date:2022-08-04

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Authors:

Chow, Yuan L.

Polo, Joel

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Article abstract of DOI:10.1039/c39810000297

While N-acetyl-N-nitrosophenylalanine thermally decomposes by the known mechanism, its carboxylate anion undergoes facile rearrangements initiated by carboxylate attack in methanol or water to give 2-methoxy- or 2-hydroxy-3-phenylpropanoic acid, respectively.

Full text of DOI:10.1039/c39810000297

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