Polynuclear organometallic helices by means of novel coupling reactions of cyclomanganated complexes with aryl-substituted diazoalkanes: Syntheses of new manganospiralenes and appended (η5-fluoren-9-yl)M(CO)3 complexes (M = Mn, Re)

DOI: 10.1021/om020116z

Source and publish data:

Organometallics p. 3519 - 3535 (2002)

Update date:2022-08-02

Topics:

Authors:

Michon, Christophe

Djukic, Jean-Pierre

Ratkovic, Zoran

Collin, Jean-Paul

Pfeffer, Michel

De Cian, André

Fischer, Jean

Heiser, Dirk

D?tz, Karl Heinz

Nieger, Martin

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Article abstract of DOI:10.1021/om020116z

Novel reactions of various cis-(LC)Mn(CO)₄ complexes (LC = a three-electron chelating ligand) with diazodiphenylmethane and 9-diazofluorene allowed the synthesis of a new type of oligomeric polynuclear manganospiralene derived from quinoxaline

Full text of DOI:10.1021/om020116z

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Product name:3-methyl-2-(2'-[tricarbonyl(η5-fluoren-9-yl)manganese(I)]phenyl)pyridine

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