Tetrahedron Letters p. 3133 - 3136 (2002)
Update date:2022-08-04
Topics:
Muthusamy, Sengodagounder
Babu, Srinivasarao Arulananda
Gunanathan, Chidambaram
Facile O-H insertion reactions of α-diazo ketones with aliphatic/aromatic alcohols or benzenethiol have been developed in the presence of indium triflate as a catalyst. These reactions provided good yields of α-alkoxy ketones. A comparative study with other Lewis acids establishes the reactivity of indium triflate in O-H insertion reactions of α-diazo ketones.
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